866455-72-3

Upstream product

• 765300-71-8 (2S)-1[(2S)-1,4-dioxaspiro[4.5]decan-2-yl]pent-4-en-2-ol 
• 866455-65-4 1-[(2S)-1,4-dioxaspiro[4,5]dec-2-yl]-4-penten-2-ol 
• 866455-67-6 (S)-1-(1,4-Dioxa-spiro[4.5]dec-2-yl)-pent-4-en-2-one 
• 866455-70-1 (S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane 

Downstream Products

• 866455-75-6 3-[3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-propionic acid (1R,3S)-3-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester 
• 71939-67-8 (R)-1-methyl-2-[(S)-6-oxo-3,6-dihydro-2H-pyran-2-yl]ethyl 3-(3,4-dihydroxyphenyl)propanoate 
• 131613-66-6 (-)-<5(S),7(R)>-7-<5-(oct-2-enolide)-3',4'-bis-(t-butyldimethylsilyloxy)>-dihydrocinnamate 
• 335161-38-1 3-[3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-propionic acid (1R,3S)-3-hydroxy-1-methyl-hex-5-enyl ester 
• 335161-39-2 Acrylic acid (S)-1-((R)-2-{3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-propionyloxy}-propyl)-but-3-enyl ester 
• 866455-60-9 (2R,4S)-4-(4-Methoxy-benzyloxy)-hept-6-en-2-ol 

Relevant academic research and scientific papers

Chelation-controlled reduction: An enantioselective synthesis of (-)-tarchonanthuslactone

The total synthesis of tarchonanthuslactone (1) has been achieved by two different routes. In the first approach, LiAlH4-LiI reduction and RCM protocols, and in the second approach, Wacker oxidation and LiAlH 4-LiI reduction were use