86649-78-7Relevant academic research and scientific papers
THE ARENE OXIDE-OXEPINE VALENCE ISOMERIZATION; A DYNAMIC NMR INVESTIGATION USING A PROCHIRAL SUBSTITUENT
Jennings, Brian W.,Rutherford, Mark,Boyd, Derek R.,Agarwal, Shiv K.,Sharma Narain D.
, p. 7551 - 7558 (1988)
The geminal α-methylene protons in 3-ethylnaphthalene-1,2-oxide show chemical shift nonequivalence in (1)H NMR spectra recorded at ambient temperature consistent with a high barrier to enantiomerization via the oxepine tautomer.The methylene protons in α-
