86652-97-3

Basic information

• Product Name: Phenylsulfonyl-8 octanol-1
• Synonyms: Phenylsulfonyl-8 octanol-1
• CAS NO: 86652-97-3
• Molecular Weight: 270.393
• Mol File: 86652-97-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenylsulfonyl-8 octanol-1(CAS DataBase Reference)
• NIST Chemistry Reference: Phenylsulfonyl-8 octanol-1(86652-97-3)
• EPA Substance Registry System: Phenylsulfonyl-8 octanol-1(86652-97-3)

Safety Data

• Hazardous Substances Data: 86652-97-3(Hazardous Substances Data)

Upstream product

• 23144-52-7 8-chlorooctan-1-ol 
• 873-55-2 sodium benzenesulfonate 

Downstream Products

• 132255-29-9 8-phenylsulfonyl-11E-hexadecen-1-ol 
• 57491-33-5 E-11-Hexadecenal 
• 61301-56-2 trans-11-hexadecen-1-ol 
• 105866-16-8 Phenylsulfonyl-8 dodecene-8E ol-1 acetate 
• 28079-04-1 (Z)-8-dodecen-1-yl acetate 
• 40642-40-8 (Z)-8-dodecenol 

Relevant articles and documents

SYNTHESES A L'AIDE DE SULFONES (XXXVII). SYNTHESE DE TROIS PHEROMONES A UNE DOUBLE LIAISON Z : Z, 8-DDA; Z, 9-DDA; Z, 9-TDA.

The title compounds Z,8-dodecen-1yl acetate, Z,9-dodecen-1yl acetate and Z,9-tetradecen-1yl-acetate have been synthesized in three efficient steps: the reaction mixture from metalated ω-hydroxy sulfones and appropriate aldehydes was quenched with acetic anhydride yielding a diastereoisomeric mixture of β-acetoxy sulfones.Convergent elimination with powdered sodium hydroxide led to the E vinylic sulfone.Stereospecific hydrogenolysis of the sulfonyl group was carried out with sodium dithionite leading to the unsaturated alcohol (> 99percent Z).