86653-09-0

Basic information

• Product Name: (S)-1-Benzenesulfonyl-decan-2-ol
• Synonyms: (S)-1-Benzenesulfonyl-decan-2-ol
• CAS NO: 86653-09-0
• Molecular Weight: 298.447
• Mol File: 86653-09-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-1-Benzenesulfonyl-decan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-Benzenesulfonyl-decan-2-ol(86653-09-0)
• EPA Substance Registry System: (S)-1-Benzenesulfonyl-decan-2-ol(86653-09-0)

Safety Data

• Hazardous Substances Data: 86653-09-0(Hazardous Substances Data)

Upstream product

• 124-19-6 nonan-1-al 
• 3112-85-4 methylphenylsulfonate 

Downstream Products

• 93423-45-1 5-octyl-4-(phenylsulfonyl)-dihydro-2(3H)-furanone 
• 17756-68-2 5-octyl-5H-furan-2-one 

Relevant articles and documents

Reactions of (2S)-1-Arenesulfonyl-2-alkanol Dianions with Aldehydes. Application to the Synthesis of Enantiomerically Pure (3S)-1-Alken-3-ols and (2E,4S)-4-hydroxy-2-alkenenitriles

Enantiomerically pure (2S)-1-arenesulfonyl-2-alkanols (1) were prepared by yeast reduction of 1-arenesulfonyl-3-chloro-2-propanones, followed by epoxydation and alkylation.Reaction of dianions of 1 with aldehydes occurred at the pro(R) position of C(1) to give 1,3-diols, which were converted to (3S)-1-alken-3-ols or (2E,4S)-4-hydroxy-2-alkenenitriles in 100percent e.e.