86660-77-7Relevant academic research and scientific papers
The 'one-pot' syntheses of α,α′-diphosphino-substituted imines: A unique reaction of bulky bis(dialkylamino)chlorophosphines
Baceiredo,Bertrand,Dyer,Fawcett,Griep-Raming,Guerret,Hanton,Russell,Williamson
, p. 591 - 596 (2001)
The reaction between various bis(dialkylamino)chlorophosphines and N-isopropyl-substituted lithium amides afforded bis(α,α′-phosphino)imines in a 'one-pot' procedure. These compounds react with sulfur to generate intramolecularly hydrogen-bonded ylide derivatives. The molecular structure of (Pr2iN)2PCH2C(=NBut) CH2P(NPri)2 has been determined by X-ray crystallography.
