866612-95-5Relevant academic research and scientific papers
Orbital-overlap control of the reactivity of a bicyclic 1-hydroxy-1,4-biradical
Yang, Chao,Xia, Wujiong,Scheffer, John R.,Botoshansky, Mark,Kaftory, Menahem
, p. 5087 - 5089 (2007/10/03)
Radical reform: Cleavage of the enantiotopic C2-C3 or C2-C3′ bonds in bicyclic 1-hydroxy-1,4-biradicals (see structure) leads to enantiomeric products. Absolute configuration correlations demonstrate that, in the crystalline state, cleavage occurs mainly
