866725-53-3Relevant academic research and scientific papers
Acetylene bridged porphyrin-monophthalocyaninato ytterbium(iii) hybrids with strong two-photon absorption and high singlet oxygen quantum yield
Ke, Hanzhong,Li, Wenbin,Zhang, Tao,Zhu, Xunjin,Tam, Hoi-Lam,Hou, Anxin,Kwong, Daniel W. J.,Wong, Wai-Kwok
, p. 4536 - 4543 (2012/07/02)
Several acetylene bridged porphyrin-monophthalocyaninato ytterbium(iii) hybrids, PZn-PcYb, PH2-PcYb and PPd-PcYb, have been prepared and characterized by 1H and 31P NMR, mass spectrometry, and UV-vis spectroscopy. Their photophysical and photochemical properties, especially the relative singlet oxygen (1O2) quantum yields and the two-photon absorption cross-section (σ2), were investigated. These three newly synthesized compounds exhibited very large σ2 values and substantial 1O2 quantum yields upon photo-excitation, making them potential candidates as one- and two-photon photodynamic therapeutic agents.
Ethyne-bridged (porphinato)zinc(II)-(porphinato)iron(III) complexes: Phenomenological dependence of excited-state dynamics upon (porphinato)iron electronic structure
Duncan, Timothy V.,Wu, Sophia P.,Therien, Michael J.
, p. 10423 - 10435 (2007/10/03)
We report the synthesis, spectroscopy, potentiometric properties, and excited-state dynamical studies of 5-[(10,20-di-((4-ethyl ester)methylene-oxy) phenyl)porphinato]zinc(II)-[5′-[(10′,20′- di-((4-ethyl ester)methylene-oxy)phenyl)porphinato]iron(III)-chl
