866825-33-4Relevant academic research and scientific papers
A Bis(thiophosphinoyl)methylene ruthenium carbene complex: Synthesis, X-ray crystal structure, and DFT calculations of its thermally promoted reverse α-hydride migration process
Cantat, Thibault,Demange, Matthieu,Mezailles, Nicolas,Ricard, Louis,Jean, Yves,Le Floch, Pascal
, p. 4838 - 4841 (2005)
The synthesis and X-ray crystal structure of a new (S,C,S)-based carbene ruthenium complex (2) are presented. The thermally promoted rearrangement of this new complex to complex 3 involves a reverse α-hydride migration, which has been investigated by DFT calculations.
Transmetalation of a nucleophilic carbene fragment: From early to late transition metals
Fustier-Boutignon, Marie,Heuclin, Hadrien,Le Goff, Xavier Frederic,Mezailles, Nicolas
, p. 3306 - 3308 (2012/04/23)
Early transition metal nucleophilic carbene complexes have been used as stoichiometric carbene transfer agents in a transmetalation process. The Royal Society of Chemistry 2012.
