866825-52-7Relevant academic research and scientific papers
Dual gold/photoredox-catalyzed C(sp)-H arylation of terminal alkynes with diazonium salts
Tlahuext-Aca, Adrian,Hopkinson, Matthew N.,Sahoo, Basudev,Glorius, Frank
, p. 89 - 93 (2015/12/30)
The arylation of alkyl and aromatic terminal alkynes by a dual gold/photoredox catalytic system is described. Using aryldiazonium salts as readily available aryl sources, a range of diversely-functionalized arylalkynes could be synthesized under mild, base-free reaction conditions using visible light from simple household sources or even sunlight. This process, which exhibits a broad scope and functional group tolerance, expands the range of transformations amenable to dual gold/photoredox catalysis to those involving C-H bond functionalization and demonstrates the potential of this concept to access AuI/AuIII redox chemistry under mild, redox-neutral conditions.
Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory
Wang, Timothy C.,Bury, Wojciech,Gómez-Gualdrón, Diego A.,Vermeulen, Nicolaas A.,Mondloch, Joseph E.,Deria, Pravas,Zhang, Kainan,Moghadam, Peyman Z.,Sarjeant, Amy A.,Snurr, Randall Q.,Stoddart, J. Fraser,Hupp, Joseph T.,Farha, Omar K.
supporting information, p. 3585 - 3591 (2015/03/30)
An isoreticular series of metal-organic frameworks (MOFs) with the ftw topology based on zirconium oxoclusters and tetracarboxylate linkers with a planar core (NU-1101 through NU-1104) has been synthesized employing a linker expansion approach. In this se
