866939-08-4Relevant articles and documents
Gold-catalyzed waste-free generation and reaction of azomethine ylides: Internal redox/dipolar cycloaddition cascade
Yeom, Hyun-Suk,Lee, Ji-Eun,Shin, Seunghoon
supporting information; experimental part, p. 7040 - 7043 (2009/04/07)
(Chemical Equation Presented) High-octane synthesis: Azomethine ylides can be generated from an internal redox reaction of a nitrone-tethered alkyne under electrophilic metal catalysis (see scheme; M=metal). This novel and atom-economical generation of an azomethine ylide does not involve potentially explosive diazo derivatives. The azomethine ylide can participate in a dipolar cycloaddition cascade to provide an azabicyclo[3.2.1]octane.