866941-35-7

Upstream product

• 24211-63-0 gomophogenin 
• 87713-47-1 3,4-di-O-benzoyl-6-deoxy-α-D-arabino-hexopyranos-2-ulosyl bromide 
• 52080-34-9 1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol 

Downstream Products

• 89103-54-8 3'-epi-gomphoside 
• 36597-51-0 gomphoside 

Relevant academic research and scientific papers

A concise and general method for doubly attaching 2-ketosugars to aglycon diols: Synthesis of the gomphosides and spectinomycin

(Chemical Equation Presented) Spectinomycin and the gomphosides: Use of 6-deoxyhexulosyl derivatives of D-glucose in Ag2CO 3-mediated glycosylation of gomphogenin and actinamine has allowed the first syntheses of cardiac glycosides with ring A-annulated sugar components (see picture; Bz = benzoyl) and an alternate synthesis of the antibiotic spectinomycin.