867064-77-5Relevant academic research and scientific papers
Formal alkyne insertion into alkoxycarbene complexes: Simple access to enantiopure group 6 alkynyl(alkoxy)carbene complexes
Barluenga, Jose,De La Rua, Ramon Bernardo,De Saa, Diana,Ballesteros, Alfredo,Tomas, Miguel
, p. 4981 - 4983 (2005)
(Chemical Equation Presented) A single (or iterative) insertion of alkyne units into metal carbene complexes, accompanied by alkoxy exchange, occurs readily to give elusive alkynyl-(alkoxy)carbenes (see scheme) as well as polyalkynyl(alkoxy)carbenes. M =
