867150-84-3

Upstream product

• 867150-83-2 1-((R)-1-Chloro-2-methyl-prop-1-ene-1-sulfinyl)-4-methyl-benzene 
• 20487-40-5 tert-butyl propionate 
• 31350-91-1 (R)-chloromethyl p-tolyl sulfoxide 

Downstream Products

• 867150-87-6 (R)-2,3,3-Trimethyl-4-((S)-toluene-4-sulfinyl)-butyric acid 
• 867150-85-4 (R)-2,3,3-Trimethyl-4-((S)-toluene-4-sulfinyl)-butyric acid tert-butyl ester 

Relevant academic research and scientific papers

An asymmetric synthesis of carboxylic acid derivatives, including lactic acid and α-amino acid derivatives, from optically active 1-chlorovinyl p-tolyl sulfoxides and ester lithium enolates with creation of chirality at the α-position

Treatment of optically active 1-chlorovinyl p-tolyl sulfoxides, which were synthesized from symmetrical ketones or methyl formate and (R)-(-)-chloromethyl p-tolyl sulfoxide in three steps, with lithium enolate of carboxylic acid tert-butyl esters gave opt

A novel method for asymmetric synthesis of both enantiomers of α-substituted carboxylic acid derivatives from optically active 1-chlorovinyl p-tolyl sulfoxides and lithium ester enolates with 1,4-chiral induction from the sulfur chiral center

Treatment of optically active 1-chlorovinyl p-tolyl sulfoxides, which were synthesized from symmetrical ketones and (R)-(-)-chloromethyl p-tolyl sulfoxide in three steps, with lithium enolate of carboxylic acid tert-butyl esters gave optically active addu