867150-88-7

Upstream product

• 31350-91-1 (R)-chloromethyl p-tolyl sulfoxide 
• 108-94-1 cyclohexanone 

Downstream Products

• 867150-90-1 tert-butyl 2-{1-[chloro(p-tolylsulfinyl)methyl]cyclohexyl}propionate 
• 867150-93-4 tert-butyl 2-{1-[chloro(p-tolylsulfinyl)methyl]cyclohexyl}butanoate 
• 956904-48-6 tert-butyl 2-benzyloxy-2-{1-[chloro(p-tolylsulfinyl)methyl]cyclohexyl}acetate 
• 956904-52-2 tert-butyl 2-dibenzylamino-2-{1-[chloro(p-tolylsulfinyl)methyl]cyclohexyl}acetate 
• 1220710-51-9 C₂₀H₂₉ClO₃S 
• 1220710-42-8 C₂₈H₃₇ClO₃S 
• 1174517-21-5 C₂₇H₃₅ClO₃S 
• 867151-00-6 (R)-2-[1-((S)-Toluene-4-sulfinylmethyl)-cyclohexyl]-butyric acid tert-butyl ester 
• 867150-97-8 (R)-2-[1-((S)-Toluene-4-sulfinylmethyl)-cyclohexyl]-propionic acid tert-butyl ester 

Relevant academic research and scientific papers

Asymmetric synthesis of bicyclo[n.1.0]alkanes by the enantioselective 1,3-CH insertion reaction of chiral magnesium carbenoids

Treatment of enantiomerically pure 1-chlorovinyl p-tolyl sulfoxides, derived from cyclic ketones and (R)-chloromethyl p-tolyl sulfoxide, with the lithium enolate of tert-butyl carboxylates gave adducts in quantitative yields as single diastereomers. The a

An asymmetric synthesis of carboxylic acid derivatives, including lactic acid and α-amino acid derivatives, from optically active 1-chlorovinyl p-tolyl sulfoxides and ester lithium enolates with creation of chirality at the α-position

Treatment of optically active 1-chlorovinyl p-tolyl sulfoxides, which were synthesized from symmetrical ketones or methyl formate and (R)-(-)-chloromethyl p-tolyl sulfoxide in three steps, with lithium enolate of carboxylic acid tert-butyl esters gave opt