867157-12-8Relevant articles and documents
Nickel-catalyzed regio- and stereoselective hydrophosphinylation of internal ynamides with H-phosphinates
Kinbara, Atsushi,Kasai, Haruka,Sato, Kaede,Watanabe, Yuri,Yamagishi, Takehiro
, p. 7068 - 7073 (2018)
A method for the catalytic hydrophosphinylation of internal ynamides with H-phosphinates has been developed for the first time. The protocol employing the catalyst generated from NiBr2 and PPh3 could be applied to several types of ynamides and H-phosphinates, affording (E)-β-aminovinylphosphinates in a highly regio- and stereoselective manner.