86723-21-9Relevant articles and documents
A hexaazatriphenylene fused large discotic polycyclic aromatic hydrocarbon with selective and sensitive metal-ion sensing properties
Qu, Wenxiu,Yuan, Wei,Li, Mengwei,Chen, Yulan
, p. 3837 - 3840 (2021)
A HAT based large PAH discotic molecule PN8 is developed. The enlarged chromophoric core and doping heteroatoms enable colorimetric and fluorometric sensing of Cu2+ and Zn2+ with highly appreciable optical changes, good selectivity and low detection limit. Moreover, PN8 was demonstrated as an excellent adsorbent to remove Cu2+ and Zn2+ from wastewater.
Synthesis and electrochromic behavior of a multi-electron redox-active N-heteroheptacenequinone
Isoda, Kyosuke,Matsuzaka, Mitsuru,Sugaya, Tomoaki,Yasuda, Takeshi,Tadokoro, Makoto
, p. 7884 - 7890 (2019/09/06)
We report a novel N-heteroheptacenequinone derivative (C6OAHCQ) as a large π-conjugated framework. C6OAHCQ shows good electron-accepting behaviour owing to eight electron-deficient imino-N atoms and two carbonyl moieties and excellent solubility in common organic solvents. When a potential between 0 and -2.20 V is applied, C6OAHCQ is able to accept four electrons, which is more than fullerene C60 (three electrons) could accept in this voltage range. Moreover, a solution of C6OAHCQ and nBu4NPF6 in CH2Cl2 exhibits a clearly reversible brown-to-green colour change, suggesting that C6OAHCQ has potential as an electrochromic material.
Synthesis and stereochemistry of long-chain quinoxaline metallocyclophanes
Howard, Mark J.,Heirtzler, Fenton R.,Dias, Sandra I. G.
, p. 2548 - 2553 (2008/09/19)
(Figure Presented) Condensation of 1,2-diamino-4,5-bis(n-alkoxy)arenes with an oligopyridyl-type α-diketone afforded a series of long-chain pyridine-quinoxaline hybrids. These were evaluated for their ability to self-assemble with tetrahedral Cu(I) and Ag