86723-23-1Relevant academic research and scientific papers
Molecular Coplanarity and Self-Assembly Promoted by Intramolecular Hydrogen Bonds
Zhu, Congzhi,Mu, Anthony U.,Lin, Yen-Hao,Guo, Zi-Hao,Yuan, Tianyu,Wheeler, Steven E.,Fang, Lei
, p. 6332 - 6335 (2016)
Active conformational control is realized in a conjugated system using intramolecular hydrogen bonds to achieve tailored molecular, supramolecular, and solid-state properties. The hydrogen bonding functionalities are fused to the backbone and precisely pr
Spectroscopic and theoretical optical properties of indoleninyl-substituted dibenzotetraaza[14]annulenes
Ramle, Abdul Q.,Karakas, Asli,Arof, Abdul K. M.,Karakaya, Mustafa,Taser, Mehmet,Gozutok, Aysun,Chin Fei, Chee,Julkapli, Nurhidayatullaili M.,Basirun, Wan J.
, p. 3566 - 3573 (2020)
Two new macrocyclic dibenzotetraaza[14]annulene (DBTAA) compounds with indolenine (5) and pyridoindolenine (6) moieties were synthesized and characterized by spectroscopy. Both DBTAAs exhibit strong UV-Vis absorption properties in the Soret band region. T
A Constrained and “Inverted” [3+3] Salphen Macrocycle with an ortho-Phenylethynyl Substitution Pattern
Torres, Tomas,Urbani, Maxence
supporting information, (2020/02/04)
A [3+3] Schiff-base salphen macrocycle (7 a) was synthesized by imine condensation between ortho-phenylenediamine and ortho-phenylethynyl-bridged bis(5-salicylaldehyde) precursors. The triangular-shaped macrocycle 7 a has a nonclassical (or “inverted”) de
Constructing a self-assembling C3-symmetric covalently linked (fused) donor-acceptor-type molecule containing a hexaazatriphenylene core
Bhanvadia, Viraj J.,Patel, Arun L.,Zade, Sanjio S.
, p. 17700 - 17707 (2018/11/01)
A C3-symmetric covalently linked (fused) molecule, HAT-IPN, comprising a 13 fused ring system was synthesized by a condensation-cyclisation reaction between hexaazatriphenylenehexacarboxylic acid trisanhydride and 4,5-diamino-1,2-dioctyloxybenzene. This fused system exhibits ambipolar behaviour due to an n-type HAT-core at the center and three outer p-type fused dialkoxybenzimidazole moieties, which is confirmed by cyclic voltammetry. The self-assembling nature of this disc-shaped donor-acceptor type system is evident in13C NMR spectroscopy, dynamic light scattering studies, differential scanning calorimetry and atomic force microscopy (AFM) images, which illustrate the formation of the one-dimensional aggregates both in solution and in the film state; indicating its potential as an active component in organic electronic devices.
Amphiphilic iron(ii) complexes with short alkyl chains-crystal packing and spin transition properties
Schlamp, Stephan,Dankhoff, Katja,Weber, Birgit
, p. 1965 - 1972 (2014/05/06)
An amphiphilic iron(ii) spin crossover complex with relatively short octyl chains was synthesised and the crystal structures of the high spin and the low spin state could be determined. In further reactions, a second modification of the hexa-coordinated c
Fluoro-functionalization of vinylene units in a polyarylenevinylene for polymer solar cells
Cardone, Antonio,Martinelli, Carmela,Losurdo, Maria,Dilonardo, Elena,Bruno, Giovanni,Scavia, Guido,Destri, Silvia,Cosma, Pinalysa,Salamandra, Luigi,Reale, Andrea,Di Carlo, Aldo,Aguirre, Aranzazu,Milian-Medina, Begona,Gierschner, Johannes,Farinola, Gianluca M.
, p. 715 - 727 (2013/06/27)
A low band-gap copolymer PDTBTFV alternating bis-thienyl-(bis-alkoxy)- benzothiadiazole blocks with difluorovinylene units and its non-fluorinated counterpart PDTBTV have been synthesized and characterized as donor materials in bulk heterojunction (BHJ) s
New octahedral, head-tail iron(II) complexes with spin crossover properties
Schlamp, Stephan,Thoma, Peter,Weber, Birgit
experimental part, p. 2759 - 2768 (2012/08/14)
The synthesis and characterisation of four new Schiff base-like ligands with long alkyl chains in the outer periphery and their iron(II) complexes with methanol and pyridine as axial ligands is reported. Two of the methanol complexes crystallise in a lipi
Capsule formation in novel cadmium cluster metallocavitands
Frischmann, Peter D.,MacLachlan, Mark J.
, p. 4480 - 4482 (2008/09/16)
We report the synthesis and characterization of a new heptanuclear cadmium cluster complex formed within a Schiff base macrocycle and study its surprising dimerization in the solid-state and solution to form capsules. The Royal Society of Chemistry.
In Situ Synthesis of Hexakis(alkoxy)diquinoxalino[2,3-a:2′,3′ -c]phenazines: Mesogenic Phase Transition of the Electron-Deficient Discotic Compounds
Ong, Chi Wi,Liao, Su-Chih,Chang, Tsu Hsing,Hsu, Hsiu-Fu
, p. 3181 - 3185 (2007/10/03)
2,3,8,9,14,15-Hexakis(alkoxy)diquinoxalino[2,3-a:2′,3′- c]phenazines with alkyl side chains varying from 6 to 12 carbon atoms were readily synthesized by the condensation of hexaketocyclohexane with the respective 1,2-bisalkoxy-4,5-diaminobenzene. Polariz
