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[2-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-5-trifluoromethyl-phenyl]-naphthalen-2-yl-methanone is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 86727-73-3 Structure
  • Basic information

    1. Product Name: [2-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-5-trifluoromethyl-phenyl]-naphthalen-2-yl-methanone
    2. Synonyms:
    3. CAS NO:86727-73-3
    4. Molecular Formula:
    5. Molecular Weight: 397.397
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 86727-73-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [2-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-5-trifluoromethyl-phenyl]-naphthalen-2-yl-methanone(CAS DataBase Reference)
    10. NIST Chemistry Reference: [2-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-5-trifluoromethyl-phenyl]-naphthalen-2-yl-methanone(86727-73-3)
    11. EPA Substance Registry System: [2-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-5-trifluoromethyl-phenyl]-naphthalen-2-yl-methanone(86727-73-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 86727-73-3(Hazardous Substances Data)

86727-73-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86727-73-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,7,2 and 7 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 86727-73:
(7*8)+(6*6)+(5*7)+(4*2)+(3*7)+(2*7)+(1*3)=173
173 % 10 = 3
So 86727-73-3 is a valid CAS Registry Number.

86727-73-3Relevant articles and documents

Syntheses of 9-(Trifluoromethyl)- and 10-(Trifluoromethyl)-7,12-dimethylbenzanthracenes

Newman, Melvin S.,Veeraraghavan, Seshadri

, p. 3246 - 3248 (1983)

4,4-Dimethyl-2-(2-lithio-4-(trifluoromethyl)phenyl)-2-oxazoline reacted with 2- and 1-naphthaldehydes to afford, after hydrolysis, 3-(2-naphthyl)-5-(trifluoromethyl)phthalide (6) and 3-(1-naphthyl)-5-(trifluoromethyl)phthalide (7), respectively.Hydriodic acid reduction of these phthalides yielded 2-(2-naphthylmethyl)-4-(trifluoromethyl)benzoic acid (8) and 2-(1-naphthylmethyl)-4-(trifluoromethyl)benzoic acid (9), which were cyclized and oxidized to 9-(trifluoromethyl)-7,12-benzanthraquinone (10) and 10-(trifluoromethyl)-7,12-benzanthraquinone (11), respectively.Reaction of these quinones with methyllithium followed by stannous chloride-hydrochloric acid reduction of the resulting diols gave 9-(trifluoromethyl)-7,12-dimethylbenzanthracene (12) and 10-(trifluoromethyl)-7,12-dimethylbenzanthracene (13), respectively.In a different route, 2-(3-(trifluoromethyl)benzoyl)-1-naphthoic acid (15), prepared from m-(trifluoromethyl)phenylmagnesium bromide (14) and 1,2-naphthalic anhydride, was reacted with methylmagnesium bromide to obtain 2--1-naphthoic acid lactone (16).Zinc-alkali reduction of 16 yielded 2--1-naphthoic acid (17), the acid chloride of wich afforded 1-acetyl-2-naphthalene (18) on treatment with lithium dimethylcuprate.Although 2--1-naphthoic acid lactone (19), obtained by the reduction of 15 with triethylsilane, underwent a reductive ring closure to 9-(trifluoromethyl)benzanthracene (20), attemped cyclization of 18 did not yield the anticipated 12.

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