867277-70-1

Basic information

• Product Name: [Co2(CO)4(μ-bis(diphenylphosphino)methane)(μ-η1,η2-(diisopropyl)aminophosphamethylene)]
• CAS NO: 867277-70-1
• Molecular Weight: 759.61
• Mol File: 867277-70-1.mol

Chemical Properties

• CAS DataBase Reference: [Co2(CO)4(μ-bis(diphenylphosphino)methane)(μ-η1,η2-(diisopropyl)aminophosphamethylene)](CAS DataBase Reference)
• NIST Chemistry Reference: [Co2(CO)4(μ-bis(diphenylphosphino)methane)(μ-η1,η2-(diisopropyl)aminophosphamethylene)](867277-70-1)
• EPA Substance Registry System: [Co2(CO)4(μ-bis(diphenylphosphino)methane)(μ-η1,η2-(diisopropyl)aminophosphamethylene)](867277-70-1)

Safety Data

• Hazardous Substances Data: 867277-70-1(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 

Relevant articles and documents

Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes: Formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2- P(NiPr2)=NR}] and diazoalkane insertions into metal-phosphorus bonds

The bridging phosphinidene complexes [Mn2(CO) 8(μ-PNiPr2)] and [Co2(CO) 4(μ-dppm)(μ-PNR2)] (NR2 = N iPr2, TMP) react with heterocumulenes RN3, CH2N2 and Ph2C=N=N to form complexes with μ-η1,η2-aminophosphaimine, μ- η1,η2-amino-phosphaalkene and μ- η1,η2-aminophosphadiphenylmethylazaimine ligands, respectively. The Royal Society of Chemistry 2005.