86728-50-9Relevant academic research and scientific papers
Cryptic stereochemistry of berberine alkaloid biosynthesis
Bjorklund, Jeffrey A.,Frenzel, Thomas,Rueffer, Martina,Kobayashi, Motomasa,Mocek, Ursula,Fox, Christina,Beale, John M.,Gr?ger, Stefan,Zenk, Meinhart H.,Floss, Heinz G.
, p. 1533 - 1545 (1995)
The cryptic stereochemistry of one-carbon transformations in berberine biosynthesis has been elucidated by the chiral methyl group methodology and tritium NMR spectroscopy. The transfer of the methyl group of AdoMet to oxygen and nitrogen occurs with comp
A Simple and Efficient Synthesis of Chiral Acetic Acid of High Optical Purity
Kobayashi, Koji,Prabhakar, K. Jadhav,Zydowsky, Thomas M.,Floss, Heinz G.
, p. 3510 - 3512 (2007/10/02)
(R)- and (S)-2H,2-3H>acetic acid of high chiral purity was synthesized in over 50 percent radiochemical yield.Reduction of 3,5-dimethoxy-2H>benzaldehyde with optically pure (+)-α-pinanyl-9-BBN and reduction of the un
