86730-92-9Relevant academic research and scientific papers
SYNTHESIS AND REACTIVITY OF MONO- AND HETERO-NUCLEAR RHODIUM(I) OR IRIDIUM(I) COMPLEXES WITH 2-(2'-PYRIDYL)BENZIMIDAZOLE
Uson, Rafael,Oro, Luis A.,Cabeza, Javier A.
, p. 105 - 116 (2007/10/02)
Rhodium(I) and iridium(I) complexes of the formulae M(PyBzIm)(diolefin), ClO4, (diolefin)M(μ-PyBzIm)AuCl, ClO4 (L = PPh3 or P(OMe)3), ClO4 and 2>ClO4 (diolefin = COD or NBD) are described.The related carbonyl derivatives M(PyBzIm)(CO)Y, ClO4 (Y = CO or PPh3), (CO)2M(μ-PyBzIm)AuCl, ClO4, 2>ClO4 and 2>ClO4 have been obtained by reaction of diolefin derivatives with carbon monoxide and triphenylphosphine.
