Cas 867376-84-9,(1S,4R)-1-((1R,3S)-1-Hydroxy-1-phenyl-hexane-3-sulfinylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one

867376-84-9

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Basic information

Product Name: (1S,4R)-1-((1R,3S)-1-Hydroxy-1-phenyl-hexane-3-sulfinylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one
Synonyms: (1S,4R)-1-((1R,3S)-1-Hydroxy-1-phenyl-hexane-3-sulfinylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one
CAS NO:867376-84-9
Molecular Formula:
Molecular Weight: 376.56
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (1S,4R)-1-((1R,3S)-1-Hydroxy-1-phenyl-hexane-3-sulfinylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one(CAS DataBase Reference)
NIST Chemistry Reference: (1S,4R)-1-((1R,3S)-1-Hydroxy-1-phenyl-hexane-3-sulfinylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one(867376-84-9)
EPA Substance Registry System: (1S,4R)-1-((1R,3S)-1-Hydroxy-1-phenyl-hexane-3-sulfinylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one(867376-84-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 867376-84-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 867376-84-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,6,7,3,7 and 6 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 867376-84:
(8*8)+(7*6)+(6*7)+(5*3)+(4*7)+(3*6)+(2*8)+(1*4)=229
229 % 10 = 9
So 867376-84-9 is a valid CAS Registry Number.

867376-84-9Upstream product

867376-84-9Downstream Products

867376-84-9Relevant academic research and scientific papers

Diastereo- and enantioselective synthesis of anti-1,3-mercapto alcohols from α,β-unsaturated ketones via tandem Michael addition-MPV reduction

Ozeki, Minoru,Nishide, Kiyoharu,Teraoka, Fumiteru,Node, Manabu

, p. 895 - 907 (2007/10/03)

A new and effective asymmetric synthesis of anti-1,3-mercapto alcohols 3 from α,β-unsaturated ketones 1 utilizing tandem Michael addition-Meerwein-Ponndorf-Verley (MPV) reduction is described. Transformation of the MPV products anti-4 via the Wagner-Meerwein rearrangement was optimized under acidic or basic conditions to afford 1,3-mercapto alcohols anti-3, depending on the substituent R2 of 4.

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