86738-26-3Relevant academic research and scientific papers
Samarium-mediated β-elimination in dihalo alcohols: Diastereoselective synthesis of (Z)-vinyl halides
Concellon, Jose M.,Bernad, Pablo L.,Perez-Andres, Juan A.
, p. 2384 - 2386 (2007/10/03)
High diastereoselectivity in β-elimination reactions of O-acetyl 1,1- dihaloalkan-2-ols to give (Z)-vinyl halides was achieved by using samarium diiodide [Eq. (1)]. The reaction was also highly diastereoselective and totally chemoselective when a mixture
Synthesis of Chiral Alk-1-ynes containing an α-Phenylethyl Group
Caporusso, Anna Maria,Lardicci, Luciano
, p. 949 - 953 (2007/10/02)
(R)-4-Phenylpent-1-yne, (R)-(1b), and (S)-5-phenylhex-1-yne, (S)-(1c), have been synthesised from the corresponding chiral alk-1-enes (2) by a stereospecific bromination-dehydrobromination procedure.On the other hand, (R)-3-phenylbut-1-yne, (R)-(1a), has
