86765-95-9Relevant academic research and scientific papers
Stereospecific endo hydride addition to cyclohexadienylmanganese complexes
Chung, Young Keun,Honig, Ephraim D.,Robinson, Ward T.,Sweigart,Connelly, Nell G.,Ittel, Steven D.
, p. 1479 - 1480 (2008/10/08)
1H NMR and X-ray structural studies show that borohydride addition to dicarbonylnitrosylcyclohexadienylmanganese cations to give cyclohexadiene complexes occurs in a stereospecific endo fashion. This is the first example of stereospecific endo hydride addition to a coordinated cyclic π-hydrocarbon.
