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SYNTHESIS AND DECOMPOSITION OF E- AND Z-3,3,5-TRISUBSTITUTED 1,2-DIOXOLANES.
Yoshida,Miura,Nojima,Kusabayashi
, p. 6279 - 6285 (2007/10/02)
The reactions of a number of ozonides and olefins in the presence of boron trifluoride-diethyl ether gave the corresponding mixtures of (E)- and (Z)-1,2-dioxolanes in 12-70% yield. The decomposition of the E-Z isomeric 1,2-dioxolanes 3a-c was undertaken under a variety of conditions, i. e. , thermal, TiCl//4-mediated, FeSO//4-catalyzed, and LiAlH//4-mediated decompositions.
