86768-68-5Relevant academic research and scientific papers
N-NITRENES. I. FORMATION OF FREE RADICALS IN THE DISSOCIATION OF DIBENZYLAMINONITRENE
Savin, V. I.,Morozov, V. I.,Kitaev, Yu. P.
, p. 866 - 870 (2007/10/02)
By ESR with spin traps it was shown that the dissociation of dibenzylaminonitrene to nitrogen and bibenzyl takes place through the formation of benzyl radicals.Various methods of generation of dibenzylaminonitrene in the presence of spin traps (2-methyl-2-nitrosopropane, nitrosodurene, phenyl-N-tert-butyl-nitrone) give spin adducts (nitroxyl radicals) stable at room temperature.The formation of two nitroxyl radicals during the dissociation of dibenzylaminonitrene labeled at one methylene group with deuterium imdicates that one molecule of dibenzylaminonitrene gives two benzyl radicals during dissociation.
