86783-14-4Relevant academic research and scientific papers
Anchimerically Assisted Substitution of a Sulfinyl Function in α-Sulfinylhydrazones by Thiols
Bosch, Hubert,Pflieger, Philippe,Mioskowski, Charles,Salaun, Jean-Pierre,Durst, Francis
, p. 2237 - 2240 (1991)
The reactivity of α-sulfinylhydrazones in the presence of thiols is reported.The reaction occurs probably via an acid catalyzed anchimerically assisted elimination/addition pathway.
SYNTHESIS OF OPTICALLY ACTIVE α-SULFINYLACETALDEHYDE
Pflieger, P.,Mioskowski, C.,Salaun, J. P.,Weissbart, D.,Durst, F.
, p. 6775 - 6778 (2007/10/02)
Optically active α-sulfinylacetaldehyde is prepared by formylation of the (R)-methyl p-tolylsulfoxide anion with N-formylpiperidine.
