868046-59-7Relevant academic research and scientific papers
1, 3, 5 - cyclohexanetriol - cis - or organic boronic acid-stable siloxy inositol complex and organic synthetic reaction using a reagent art
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Paragraph 0167; 0168; 0184, (2017/06/02)
PROBLEM TO BE SOLVED: To provide a stable ate-type complex of an organoboronic acid as a reagent for organic synthesis reaction; and manufacturing techniques thereof.SOLUTION: A stable ate-type complex of an organoboronic acid with scyllo-inositol or 1,3,5-cis-cyclohexanetriol comprises an anion represented by the specified general formula (I) or (II) as a constituent. In the formula, Rand Reach represent an alkyl group, alkenyl group, alkynyl group, aryl group, heterocyclic group or aralkyl group which may have substituents.
Palladium supported on aminopropyl-functionalized polymethylsiloxane microspheres: Simple and effective catalyst for the Suzuki-Miyaura C-C coupling
Zawartka, Wojciech,P?piech, Piotr,Cypryk, Marek,Trzeciak, Anna M.
, p. 230 - 235 (2015/07/28)
Abstract A palladium catalyst, obtained in the reaction of PdCl2(MeCN)2 with microspheric aminopropyl polymethylsiloxane, was used in the Suzuki-Miyaura cross-coupling of various aryl bromides with phenylboronic acids. Catalytic reactions, performed at 80°C in a 2-propanol/water mixture, led to high yields of non-symmetric biphenyls. In recycling experiments, excellent results (up to 100%) were obtained in ten subsequent runs. Efficient separation of the catalyst from organic products was achieved by simple filtration due to the properties of microspheres.
Cyclic thiourea/urea functionalized triphenylamine-based dyes for high-performance dye-sensitized solar cells
Wu, Zhisheng,An, Zhongwei,Chen, Xinbing,Chen, Pei
supporting information, p. 1456 - 1459 (2013/07/05)
Six cyclic thiourea/urea functionalized triphenylamine-based dyes (AZ1-AZ6) containing 2-cyanoacrylic acid as an acceptor and various linkers (phenyl, biphenyl, and bithiophene) were synthesized. They exhibited high photovoltaic performance owing to an improved short-circuit photocurrent density (J sc) and open-circuit voltage (Voc). Among them, AZ6 bearing a cyclic thiourea group and bithiophene linker showed the highest power conversion efficiency (PCE) up to 7.29%, which was comparable to that of N719 (PCE = 7.36%).
Three-dimensional four-connecting organic scaffolds with a twist: Synthesis and self-assembly
Moorthy, Jarugu Narasimha,Natarajan, Ramalingam,Venugopalan, Paloth
, p. 8568 - 8571 (2007/10/03)
We have synthesized a novel class of four-connecting three-dimensional molecular scaffolds 2-5 based on biaryls for supramolecular self-assembly. The X-ray crystal structure analysis of 2 with ethanol reveals a novel O-H...O hydrogen-bonded helical self-a
