86810-00-6Relevant articles and documents
CYANOETHYLATION OF 2-PIPERIDINOMETHYLENECYCLOHEXANONE
Dyusenova, Z. I.,Erzhanov, K. B.,Polatbekov, N. P.,Alekseeva, N. N.
, p. 1112 - 1115 (2007/10/02)
2-Piperidinomethylenecyclohexanone reacts with acrylonitrile to form mono-, di-, tri-, and tetracyanoethylation products, depending on the ratio. 2-(β-Cyanoethyl)-, 2,6-di(β-cyanoethyl)-, and 2,6,6-tri(β-cyanoethyl)-2-piperidino-methylenecyclohexanone have been obtained.In the case of tetracyanoethylation, the fourth cyanoethyl group occupies the site of the piperidine radical.The conditions for the synthesis of 6-(β-cyanoethyl)-2-piperidinomethylenecyclohexanone through the corresponding enamine have been developed.