868162-40-7Relevant academic research and scientific papers
Soluble and insoluble polymeric 1,3-dithiane reagents for the synthesis of aldehydes from alkyl halides
Bertini, Vincenzo,Lucchesini, Francesco,Pocci, Marco,Alfei, Silvana
, p. 9519 - 9526 (2007/10/03)
Through the synthesis and study of model systems as proper dithiane derivatives, vinyl monomers and soluble copolymeric reagents containing 2-unsubstituted 1,3-dithiane rings, we attained the key synthon 1,3-dithiane-5-methanol. Through its reaction with commercial resins, new polymeric reagents useful for supported organic synthesis and combinatorial chemistry were developed. Exploiting the reactivity of position 2 in 1,3-dithiane rings, such polymeric reagents were employed in the production of aldehydes from alkyl halides through a process entirely free from unpleasant odors.
