86834-01-7Relevant academic research and scientific papers
Acid-catalyzed isomerization of caryophyllene in the presence of SiO2 and Al2O3 impregnated with sulfuric acid
Romanenko,Tkachev
, p. 1051 - 1058 (2018/10/02)
The conversion of caryophyllene upon contact with Al2O3 and SiO2 impregnated with sulfuric acid was carried out, and the components of the resulting mixtures were identified. Having in hands such “standard” mixtures greatl
REDUCTION OF CARYOPHYLLENE AND ISOCARYOPHYLLENE 4,5-EPOXIDES WITH LITHIUM IN LIQUID AMMONIA
Tkachev, A. V.
, p. 109 - 118 (2007/10/02)
The reduction of the stereoisomeric 4,5-epoxy derivatives of the caryophyllene series with lithium in liquid ammonia gives the products from C-C cyclization with participation of the 8,13-double bond in addition to the "normal" reduction products, i.e., the 4-hydroxy- and 5-hydroxycaryophyllene compounds.The chemical structure and configuration of both the "normal" reduction products and the cyclocaryophyllane compounds containing the tricyclo2,5>undecane skeleton were established by analysis of the 1H and 13C NMR spectra and the optical rotatory dispersion curves.
