868398-01-0Relevant academic research and scientific papers
Highly enantioselective Cu-catalyzed conjugate addition-elimination of activated ally lie acetates with glycine derivatives
Chen, Chun-Gen,Hou, Xue-Long,Pu, Lin
supporting information; experimental part, p. 2073 - 2075 (2009/10/10)
The reaction of a glycinate Schiff base with the activated alkyl- and aryl-substituted allylic acetates afforded 4-alkylidenylglutamic acid derivatives in high yields and high enantioselectivities by using Cu/P,N-FcPhox as the catalyst.
Catalytic enantioselective synthesis of glutamic acid derivatives via tandem conjugate addition - Elimination of activated allylic acetates under chiral PTC conditions
Ramachandran, P. Veeraraghavan,Madhi, Sateesh,Bland-Berry, Layla,Reddy, M. Venkat Ram,O'Donnell, Martin J.
, p. 13450 - 13451 (2007/10/03)
A new, general, and practical procedure for the asymmetric synthesis of 4-alkylidenyl glutamic acid derivatives via a catalytic enantioselective tandem conjugate addition-elimination on allylic acetates under chiral phase-transfer conditions is reported.
