86840-48-4Relevant academic research and scientific papers
Carbene Reactions, XVII. Nitrile Ylides via 1,1-Elimination
Hoffmann, Reinhard W.,Barth, Wolfgang
, p. 634 - 642 (2007/10/02)
The 3-aminoquadricyclane-3-carbonitrile 7 decomposed upon vapor phase thermolysis into benzene and cyano(dimethylamino)carbene 15.Thermolysis of the corresponding benzylidene derivative 20 liberated the 1,3-dipole 21, which eventually leads to 1-isoindolecarbonitrile 23.The nitrile ylide 26 liberated similarly furnished the bicyclic compound 27 via intramolecular 1,3-dipolar addition.
