868562-43-0Relevant articles and documents
Exploiting the Pd- and Ru-catalyzed cycloisomerizations: Enantioselective total synthesis of (+)-allocyathin B2
Trost, Barry M.,Dong, Li,Schroeder, Gretchen M.
, p. 10259 - 10268 (2007/10/03)
Pd- and Ru-catalyzed cycloisomerizations of 1,6-enynes are compared and contrasted. Such considerations led to the enantioselective synthesis of a cyathin terpenoid, (+)-allocyathin B2 (1). The synthesis features a Pd-catalyzed asymmetric allyl