868607-58-3Relevant academic research and scientific papers
Examination of the pyridine binding to the bifunctional lewis acid B,B′-diphenyldiboradiferrocene
Pakkirisamy, Thilagar,Venkatasubbaiah, Krishnan,Kassel, W. Scott,Rheingold, Arnold L.,Jaekle, Frieder
, p. 3056 - 3064 (2009/02/05)
The binding behavior of the bifunctional Lewis acid (η5- C5H5Fe)2[μ-(C5H 3(BPh))2] (3) toward different pyridine derivatives as the Lewis base has been investigated. The 1:1 and
Reversible expansion and contraction of a 1,2-diborylated ferrocene dimer promoted by redox chemistry and nucleophile binding
Venkatasubbaiah, Krishnan,Zakharov, Lev N.,Kassel, W. Scott,Rheingold, Arnold L.,Jaekle, Frieder
, p. 5429 - 5433 (2007/10/03)
(Chemical Equation Presented) Two Bs in a pod: The first 1,2-diborylated ferrocene (see structure) was obtained upon reaction of PhBCl2 with 1,1′-bis(trimethylstannyl)ferrocene. Conformational changes in this highly rigid species are triggered either through redox chemistry or the binding of nucleophiles, to render the complex an interesting candidate for the design of new types of molecular machines.
