868615-30-9Relevant academic research and scientific papers
Asymmetric synthesis of the tricyclic core of cyathin diterpenoids via intramolecular Heck reaction
Drège, Emmanuelle,Morgant, Georges,Desma?le, Didier
, p. 7263 - 7266 (2005)
The enantioselective synthesis of the ketones 3 which displays the carbon core of NGF-inducing cyathane diterpenes is described. The key tricyclic trienone 22 was assembled in 13 steps from Michael adduct (R)-8a via intramolecular Heck cyclization of the
Synthetic studies on cyathin terpenoids: Enantioselective synthesis of the tricyclic core of cyathin through intramolecular Heck cyclisation
Drege, Emmanuelle,Tominiaux, Cyrille,Morgant, Georges,Desmaele, Didier
, p. 4825 - 4840 (2007/10/03)
An enantioselective synthesis of the tricyclic ketone (+)-5, which displays the carbon core of NGF-inducing cyathane diterpenes, has been completed according to a strategy in which the key step was the intramolecular Heck reaction of the AC subunit 49 est
