86863-44-7

Upstream product

• 86863-43-6 Benzoic acid (1S,2S,4aS,4bS,8aS,9R,10aS)-2-benzyloxy-9-hydroxy-1,4a-dimethyl-6-oxo-1,3,4,4a,4b,5,6,9,10,10a-decahydro-2H-phenanthren-8a-ylmethyl ester 
• 114968-50-2 Benzoic acid (1S,2S,4aS,4bS,8aS,9R,10aS)-2-benzyloxy-9-(2-methoxy-ethoxymethoxy)-1,4a-dimethyl-6-oxo-1,3,4,4a,4b,5,6,9,10,10a-decahydro-2H-phenanthren-8a-ylmethyl ester 
• 541-88-8 Chloroacetic anhydride 
• 84132-46-7 4a,5,6,7,8,8aα-hexahydro-7β-(benzyloxy)-4aβ,8α-dimethyl-2(1H)-oxonaphthalene-3-carboxaldehyde 
• 86863-42-5 3β-(benzyloxy)-7α-hydroxy-8β-(hydroxymethyl)-19-nor-9β-podocarp-13-en-12-one 
• 86863-43-6 3β-(benzyloxy)-7α-hydroxy-8β-((benzyloxy)methyl)-19-nor-9β-podocarp-13-en-12-one 

Downstream Products

• 86863-46-9 3β-(benzyloxy)-20-hydroxy-21-nor-9β-picrasan-12-one benzoate 
• 86863-45-8 3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one 

Relevant academic research and scientific papers

A LEWIS ACID-CATALYZED PROCEDURE FOR THE CONVERSION OF 2-METHOXYETHOXYMETHYL ETHERS TO CARBOXYLIC ESTERS

A procedure for the conversion of 2-methoxyethoxymethyl (MEM) ethers to carboxylic esters employed ferric chloride (0.4 equivalents) and a carboxulic anhydride (14 equivalents) and exibited selectivity for the MEM ether functionality in the presence of benzyl ethers.

Quassinoids. 2. Synthesis of an ABCD Ring Precursor Involving a Lactonization Induced by Iodotrimethylsilane

The Diels-Alder reaction of 3-formyl-4a,5,6,7,8,8aα-hexahydro-7β-(benzyloxy)-4aβ,8α-dimethylnaphthalen-2(1H)-one with 1-methoxy-3-(trimethylsilyloxy)-1,3-butadiene in benzene at 25 deg C furnished an extremely acid-labile Diels-Alder adduct, 3β-(benzyloxy