868761-01-7

Basic information

• Product Name: Silane, [difluoro(phenylseleno)methyl]trimethyl-
• CAS NO: 868761-01-7
• Molecular Formula: C10H14F2SeSi
• Molecular Weight: 279.263
• Mol File: 868761-01-7.mol

Chemical Properties

• CAS DataBase Reference: Silane, [difluoro(phenylseleno)methyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [difluoro(phenylseleno)methyl]trimethyl-(868761-01-7)
• EPA Substance Registry System: Silane, [difluoro(phenylseleno)methyl]trimethyl-(868761-01-7)

Safety Data

• Hazardous Substances Data: 868761-01-7(Hazardous Substances Data)

Upstream product

• 645-96-5 Benzeneselenol 
• 1666-13-3 diphenyl diselenide 

Downstream Products

• 1233948-91-8 (2S,3R,4R)-3,4-bis(O-benzyl)-1,1-difluoro-1-phenylselanyl-hex-5-ene-2,3,4-triol 
• 1233948-94-1 (2S,3R,4S)-3,4-bis(O-methoxymethyl)-1,1-difluoro-1-phenylselanyl-hex-5-ene-2,3,4-triol 
• 1233949-12-6 (R(S),2S,3R,4R)-3,4-bis(benzyloxy)-2-tert-butanesulfinamido-1,1-difluoro-1-phenylselanyl-hex-5-ene 
• 1233949-19-3 (S(S),2R,3R,4R)-3,4-bis(benzyloxy)-2-tert-butanesulfinamido-1,1-difluoro-1-phenylselanyl-hex-5-ene 
• 1201913-22-5 (2R,3S,4R)-1,1-difluoro-1-phenylselanyl-hex-5-ene-2,3,4-triol 
• 1359718-17-4 (SS,2R,3R,4R)-2-tert-butanesulfinamido-3,4-(O-isopropylidene)-6-trimethylsilyl-1,1-difluoro-1-phenylselanyl-hex-5-yne 
• 1201913-20-3 (2S,3R,4R)-3,4-O-isopropylidene-1,1-difluoro-1-phenylselanyl-hex-5-ene-2,3,4-triol 
• 1201913-21-4 (2S,3R,4S)-3,4-bis(O-benzyl)-1,1-difluoro-1-phenylselanyl-hex-5-ene-2,3,4-triol 
• 1201913-23-6 (2R,3S,4R)-3,4-bis(O-benzoyl)-1,1-difluoro-1-phenylselanyl-hex-5-ene-2,3,4-triol 

Relevant articles and documents

Synthesis and transformation of [difluoro(phenylseleno)methyl]- trimethylsilane

A novel and efficient strategy was developed to synthesize [difluoro(phenylseleno)methyl]trimethylsilane (PhSeCF2-TMS, 2), which was further utilized as a nucleophilic difluoromethylating reagent to incorporate the difluoro-(phenylseleno)methyl (PhSeCF2) group into carbonyl compounds in good yields. The resulting PhSeCF2-containing alcohols 3 could be conveniently converted into corresponding difluoromethyl alcohols 4 by a radical deselenylation.