868851-46-1

Basic information

• Product Name: (1R)-3-bromo-(4-diphenylphosphino-2,5-dimethylthienyl-3)-1,7,7-trimethylbicyclo[2.2.1]heptene-2
• Synonyms: (1R)-3-bromo-(4-diphenylphosphino-2,5-dimethylthienyl-3)-1,7,7-trimethylbicyclo[2.2.1]heptene-2
• CAS NO: 868851-46-1
• Molecular Weight: 509.49
• Mol File: 868851-46-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R)-3-bromo-(4-diphenylphosphino-2,5-dimethylthienyl-3)-1,7,7-trimethylbicyclo[2.2.1]heptene-2(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-3-bromo-(4-diphenylphosphino-2,5-dimethylthienyl-3)-1,7,7-trimethylbicyclo[2.2.1]heptene-2(868851-46-1)
• EPA Substance Registry System: (1R)-3-bromo-(4-diphenylphosphino-2,5-dimethylthienyl-3)-1,7,7-trimethylbicyclo[2.2.1]heptene-2(868851-46-1)

Safety Data

• Hazardous Substances Data: 868851-46-1(Hazardous Substances Data)

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 55057-87-9 endo-3-bromo-d-camphor 
• 868851-44-9 (1R)-3-bromo-2-bornen-2-yl trifluoromethanesulfonate 
• 869650-08-8 3-bromo-2,5-dimethylthienyl-4-magnesium bromide 
• 868851-45-0 (1R)-3-bromo-2-(4-bromo-1,5-dimethyl-3-thienyl)bornylene 

Downstream Products

• 868851-47-2 [(1S,4R)-3-[4-(diphenylphosphino)-2,5-dimethyl-3-thienyl]-4,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl]diphenylphosphine 
• 1272755-16-4 (1R)-3-di-(3,5-dimethylphenyl)phosphino-(4-diphenylphosphino-2,5-dimethylthienyl-3)-1,7,7-trimethylbicyclo[2.2.1]heptene-2 

Relevant articles and documents

Cycloolefin phosphine ligands and their use in catalysis

The present invention concerns novel bidentante optionally N-containing P-ligands of general formula (I) embracing a two-ring-system and processes for synthesizing them, transition metal complexes of these compounds and their use as catalysts.