868948-66-7

Basic information

• Product Name: (3S,5R)-3-Acetoxymethyl-5-[(S)-1-(allyl-tert-butoxycarbonyl-amino)-but-3-enyl]-piperidine-1-carboxylic acid benzyl ester
• Synonyms: (3S,5R)-3-Acetoxymethyl-5-[(S)-1-(allyl-tert-butoxycarbonyl-amino)-but-3-enyl]-piperidine-1-carboxylic acid benzyl ester
• CAS NO: 868948-66-7
• Molecular Weight: 500.635
• Mol File: 868948-66-7.mol

Chemical Properties

• CAS DataBase Reference: (3S,5R)-3-Acetoxymethyl-5-[(S)-1-(allyl-tert-butoxycarbonyl-amino)-but-3-enyl]-piperidine-1-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5R)-3-Acetoxymethyl-5-[(S)-1-(allyl-tert-butoxycarbonyl-amino)-but-3-enyl]-piperidine-1-carboxylic acid benzyl ester(868948-66-7)
• EPA Substance Registry System: (3S,5R)-3-Acetoxymethyl-5-[(S)-1-(allyl-tert-butoxycarbonyl-amino)-but-3-enyl]-piperidine-1-carboxylic acid benzyl ester(868948-66-7)

Safety Data

• Hazardous Substances Data: 868948-66-7(Hazardous Substances Data)

Upstream product

• 868948-71-4 (3S,5R)-3-Acetoxymethyl-5-((S)-1-amino-but-3-enyl)-piperidine-1-carboxylic acid benzyl ester 
• 868948-72-5 (3S,5R)-3-Acetoxymethyl-5-((S)-1-tert-butoxycarbonylamino-but-3-enyl)-piperidine-1-carboxylic acid benzyl ester 
• 106-95-6 allyl bromide 

Downstream Products

• 475301-86-1 (+)-sparteine surrogate 
• 868948-69-0 (2S,3'R,5'S)-5'-Methanesulfonyloxymethyl-1,2,3,6,3',4',5',6'-octahydro-2'H-[2,3']bipyridinyl-1'-carboxylic acid benzyl ester 
• 868948-73-6 (2S,3'R,5'S)-5'-Acetoxymethyl-1,2,3,6,3',4',5',6'-octahydro-2'H-[2,3']bipyridinyl-1'-carboxylic acid benzyl ester 
• 868948-68-9 (2S,3'R,5'S)-5'-Hydroxymethyl-1,2,3,6,3',4',5',6'-octahydro-2'H-[2,3']bipyridinyl-1'-carboxylic acid benzyl ester 
• 868948-70-3 1,5,6,8,11,11a-hexahydro-2H,4H-1,5-methano-pyrido[1,2-a][1,5]diazocine-3-carboxylic acid benzyl ester 
• 868948-65-6 5'-acetoxymethyl-3,6,3',4',5',6'-hexahydro-2H,2'H-[2,3']bipyridinyl-1,1'-dicarboxylic acid 1'-benzyl ester 1-tert-butyl ester 

Relevant articles and documents

Chiral diamines for asymmetric synthesis: An efficient RCM construction of the ligand core of (-)- and (+)-sparteine

An efficient RCM-based approach was applied to the total asymmetric synthesis of a tricyclic diamine and, formally, of its enantiomer, widely known as efficient and versatile chiral ligands of the sparteine-like type.