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NICHT-SYMMETRISCHE (BUTADIIN)DIAMINE
Feustel, Michael,Himbert, Gerhard
, p. 2165 - 2168 (2007/10/02)
By succesive tratment with butyllithium, bromine cyanide and secondary aliphatic amines the N-(3,4,4-trichloro-3-buten-1-ynyl)anilines 4 are transformed into the butadiynes 7, bearing two different amino groups.They react differently fast with electrophiles thus leading to the products 9 and 10 with one intact aminoacetylene unit.
