869005-76-5Relevant academic research and scientific papers
Dual Role of H2O2 in Palladium-Catalyzed Dioxygenation of Terminal Alkenes
Huang, Jiuzhong,Li, Jianxiao,Zheng, Jia,Wu, Wanqing,Hu, Weigao,Ouyang, Lu,Jiang, Huanfeng
supporting information, p. 3354 - 3357 (2017/07/13)
A palladium-catalyzed, environmentally friendly dioxygenation reaction of simple alkenes has been developed that enabled rapid assembly of valuable α-hydroxy ketones with high atom economy. Notably, control experiments and 18O isotope-labeling experiments established that H2O2 played a dominant dual role in this transformation.
Synthesis of three carbon atom bridged 2,4-diaminopyrrolo[2,3-d]- pyrimidines as nonclassical dihydrofolate reductase inhibitors
Gangjee, Aleem,Ye, Zhengqu,Queener, Sherry F.
, p. 1127 - 1133 (2007/10/03)
A series of seven nonclassical three carbon atom bridged 2,4-diamino-5-substituted-pyrrolo[2,3-d]-pyrimidines 1a-g were synthesized as potential inhibitors of dihydrofolate reductase. Selective oxidation of diols 7a-g affords oe-hydroxy ketones 8a-g. Subs
