86901-23-7Relevant academic research and scientific papers
Calcium Amido Complexes Coordinated by Tridentate Amidinate Ligands: Synthesis, Structures and Catalytic Activity in Olefin Hydrophosphination and Polymerization of Cyclic Esters
Tolpygin, Aleksei O.,Cherkasov, Anton V.,Fukin, Georgy K.,Kovylina, Tatyana A.,Lyssenko, Konstantin A.,Trifonov, Alexander A.
, p. 4289 - 4296 (2019/08/15)
The reactions of [(Me3Si)2N]2Ca(thf)2 with amidines 2-(Ph2P=NPh)C6H4NHC(tBu)=N(2,6-R2C6H3) {R = iPr (L1H); R = Me (L2H)} af
Exploration of tin-catalyzed phosphine dehydrocoupling: Catalyst effects and observation of tin-catalyzed hydrophosphination
Erickson, Karla A.,Dixon, Lily S.H.,Wright, Dominic S.,Waterman, Rory
supporting information, p. 141 - 145 (2015/01/09)
The phosphine substrate scope in dehydrocoupling reactions catalyzed by Cp?2SnCl2 (Cp? = pentamethylcyclopentadienyl, 1) have been explored. Catalyst variants R2SnX2 (R = Cp?, Ph; X = Cl, Me, Ph) were also tested, which revealed that activity is dependent on the Cp? ligands as well as more electron withdrawing X ligands. Steric factors at the phosphine substrate are also important. Compound 1 was found to be a catalyst for hydrophosphination of styrene, 2,3-dimethylbutadiene, and diphenylacetylene with phenylphosphine, which is the first example of a p-block catalyst for hydrophosphination.
1-Phenyl-cis-3a,7a-dihydrophosphindole and Its Properties
Quin, Louis D.,Rao, Nandakumar S.
, p. 3754 - 3759 (2007/10/02)
Deoxygenation of the dimer of 1-phenylphosphole oxide gives the diphosphine, whose thermal decomposition provides a useful route to r-1-phenyl-c-3a,c-7a-dihydrophosphindole.In the gas phase in the temperature range 345-370 deg C the dihydrophosphindole un
