869062-12-4Relevant academic research and scientific papers
Atom-economic and stereoselective syntheses of the ring A and B subunits of the bryostatins
Trost, Barry M.,Yang, Hanbiao,Brindle, Cheyenne S.,Dong, Guangbin
, p. 9777 - 9788 (2011)
This article describes chemoselective and atom-economic methods for the stereoselective assembly of the ring A and B subunits of bryostatins. A Ru-catalyzed tandem alkene-alkyne coupling/Michael addition reaction was developed and applied to the synthesis
A Ru-catalyzed tandem alkyne-enone coupling/Michael addition: Synthesis of 4-methylene-2,6-cis-tetrahydropyrans
Trost, Barry M.,Yang, Hanbiao,Wuitschik, Georg
, p. 4761 - 4764 (2007/10/03)
(Chemical Equation Presented) A Ru-catalyzed tandem alkyne-enone coupling/Michael addition reaction is reported. It provides an efficient, atom-economic entry to 4-methylene-2,6-cis-tetrahydropyrans from simple, readily available homopropargylic alcohols
