86925-63-5

Upstream product

• 119561-09-0 2,3-Dimethyl-2-butenyl p-methylphenyl sulfide 
• 5072-70-8 1-bromo-2,3-dimethyl-2-butene 
• 563-79-1 2,3-Dimethyl-2-butene 

Downstream Products

• 120987-27-1 2,3-dimethyl-4-p-tolylsulphonylnona-2,8-diene 
• 114597-44-3 2-Methyl-3-(toluene-4-sulfonylmethyl)-but-3-en-2-yl-hydroperoxide 
• 114597-45-4 (S)-2,3-Dimethyl-1-(toluene-4-sulfonyl)-but-3-en-2-yl-hydroperoxide 
• 114597-45-4 2,3-Dimethyl-1-(toluene-4-sulfonyl)-but-3-en-2-yl-hydroperoxide 
• 122145-19-1 2-Methyl-3-(toluene-4-sulfonylmethyl)-but-3-en-2-ol 
• 122145-20-4 (S)-2,3-Dimethyl-1-(toluene-4-sulfonyl)-but-3-en-2-ol 
• 86925-78-2 2,2,3-trimethyl-3-(p-tolylsulphonylmethyl)oxiran 

Relevant academic research and scientific papers

Reactions of an Allylic Sulfide, Sulfoxide, and Sulfone with Singlet Oxygen. The Observation of a Remarkable Diastereoselective Oxidation

The reactions of singlet oxygen with 1--2,3-dimethyl-2-butene (6), 1--2,3-dimethyl-2-butene (7), and 2,3-dimethyl-2-butenyl p-methylphenyl sulfide (8) have been examined.The formation of transient intermediates and products in the reaction of 8 have been followed as a function of extent of reaction and a remarkable diastereoselective reaction has been uncovered.The implications of this discovery for the mechanism of sulfide oxidation is discussed.