86926-86-5Relevant academic research and scientific papers
Redox-Switched Crown Ethers. 1. Redox-Coupled Control of Metal-Ionophore Interactions and Their Application to Membrane Transport
Shinkai, Seiji,Inuzuka, Kenichi,Hara, Kenzo,Sone, Takaaki,Manabe, Osamu
, p. 2150 - 2155 (2007/10/02)
Polyether ionophores with redox-functional thiol groups were synthesized: they are a diaza-18-crown-6 with a disulfide cap that exhibits redox-responsive interconversion between crown (1red) and cryptand (1ox) and tri- and tetra(oxye
REDOX-SWITCHED CROWN ETHERS. CROWN-CRYPTAND INTERCONVERSION COUPLED WITH REDOX OF THIOL GROUPS
Shinkai, Seiji,Inuzuka, Kenichi,Manabe, Osamu
, p. 747 - 750 (2007/10/02)
A crown ether capped with a redox-functionalized thiol-disulfide couple was synthesized.The oxidized form with an ionophoric cap binds K+, Rb+, and Cs+ more efficiently than the reduced form with two lariattype groups.This
