869336-47-0Relevant articles and documents
Stereocontrolled synthesis of spiroketals via a remarkable methanol-induced kinetic spirocyclization reaction
Potuzak, Justin S.,Moilanen, Sirkka B.,Tan, Derek S.
, p. 13796 - 13797 (2005)
A methanol-induced kinetic spiroketalization reaction has been developed for the stereocontrolled target- and diversity-oriented synthesis of spiroketals. In contrast to existing methods for spiroketal synthesis, this reaction does not depend on thermodyn
Stereoselective synthesis of benzannulated spiroketals: Influence of the aromatic ring on reactivity and conformation
Liu, Guodong,Wurst, Jacqueline M.,Tan, Derek S.
supporting information; scheme or table, p. 3670 - 3673 (2011/03/18)
Image Presented A systematic stereocontrolled synthesis of benzannulated spiroketals has been developed, using kinetic spirocyclization reactions of glycal epoxides, leading to a new AcOH-induced cyclization and valuable insights into the reactivity and c