869367-94-2

Basic information

• Product Name: (5R,4'S)-4-benzyl-7,7-dibromo-5-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-6-methoxy-3-oxa-4-azabicyclo[4.1.0]heptane
• Synonyms: (5R,4'S)-4-benzyl-7,7-dibromo-5-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-6-methoxy-3-oxa-4-azabicyclo[4.1.0]heptane
• CAS NO: 869367-94-2
• Molecular Weight: 477.193
• Mol File: 869367-94-2.mol

Chemical Properties

• CAS DataBase Reference: (5R,4'S)-4-benzyl-7,7-dibromo-5-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-6-methoxy-3-oxa-4-azabicyclo[4.1.0]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (5R,4'S)-4-benzyl-7,7-dibromo-5-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-6-methoxy-3-oxa-4-azabicyclo[4.1.0]heptane(869367-94-2)
• EPA Substance Registry System: (5R,4'S)-4-benzyl-7,7-dibromo-5-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-6-methoxy-3-oxa-4-azabicyclo[4.1.0]heptane(869367-94-2)

Safety Data

• Hazardous Substances Data: 869367-94-2(Hazardous Substances Data)

Upstream product

• 75-25-2 Bromoform 
• 227622-64-2 (3R,4'S)-2-benzyl-3-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-4-methoxy-3,6-dihydro-2H-1,2-oxazine 

Downstream Products

• 869367-96-4 (3R,4'S)-2-benzyl-5-bromo-3-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-4,4-dimethoxy-2,3,4,7-tetrahydro-1,2-oxazepine 

Relevant articles and documents

Ring enlargement of enantiopure 1,2-oxazines to 1,2-oxazepine derivatives and their palladium-catalyzed couplings

Phase-transfer-catalyzed cyclopropanation of enantiopure 1,2-oxazine derivatives anti-1a,b or syn-1 followed by solvolysis of the resulting geminal dibromocyclopropane intermediates afforded the expected ring-expanded products, namely 1,2-oxazepines anti-