869378-57-4Relevant academic research and scientific papers
Activation of C-H bonds of arenes: Selectivity and reactivity in bis(pyridyl) platinum(II) complexes
Zhang, Fenbao,Kirby, Christopher W.,Hairsine, Douglas W.,Jennings, Michael C.,Puddephatt, Richard J.
, p. 14196 - 14197 (2005)
The reaction of [PtMe2(NN)] and B(C6F5)3/H2O in CF3CH2OH with arenes Ar-H gives [PtAr{HOB(C6F5)3}(LL)] if the bis(pyridyl) ligand NN forms a six-membered, but not five-membered, chelate ring; methyl-substituted arenes give selectivity for metalation of meta > para ? ortho, but methoxy-substituted arenes give ortho ? meta, para. Copyright
