86952-12-7Relevant academic research and scientific papers
Ambivalent Reactions of Phosphanes Metallated in α-Position with n-Butyllithium
Appel, Rolf,Haubrich, Gerhard,Knoch, Falk
, p. 2063 - 2075 (2007/10/02)
The reaction of diphenyl(trimethylsilylmethyl)phosphane (1) with n-butyllithium yields the lithium methanide 2, which reacts with chlorotrimethylsilane to form diphenylphosphane (3).Repeated lithiation yields the ambivalent inte
Some phosphorus Derivatives
Eaborn, Colin,Retta, Negussie,Smith, J. David
, p. 905 - 910 (2007/10/02)
Treatment of Li with PPh2Cl gave the phosphine PPh2, which, in spite of the steric crowding caused by the silicon ligand, was readily converted into the phosphonium salts Ph2H>I and Ph2Me>I; the latter on heating gave the ylid MePh2PC(SiMe3)2.In methanol at room temperature the phosphine PPh2 readily loses one Me3Si group to give PPh2; the remaining Me3Si groups are lost successively, with decreasing ease, giving finally PPh2Me.These Si-C bond cleavages are catalysed by acid but inhibited by base, and it is suggested that the initial step is protonation of the phosphine.The quaternary salt Ph2Me>I successively loses its Me3Si groups very readily in methanol, ultimately to give I.
